File:Quantum ideal gas chemical potential 3d.svg

Summary

Description
English: Chemical potential of classical ideal gas and quantum ideal gases (Fermi gas, Bose gas) as a function of temperature, for a fixed density of particles. This is for the case of non-relativistic (massive, slow) particles in three dimensions.

A few features can be seen:

  • As temperature increase, the Fermi and Bose gases approach the classical gas line, gradually.
  • The classical gas has an interesting non-monotonic behaviour, but the quantum gases are monotonic (note that in 1D, however, the Fermi gas is also non-monotonic).
  • The Fermi gas is always higher chemical potential, and Bose gas is lower chemical potential, compared to classical ideal gas.
  • The * marker indicates the upper temperature of Bose condensation. Moving below this temperature, the chemical potential is pinned to ε0, which is the energy of a particle at rest (i.e. the per-particle potential energy).
  • The Fermi gas at low T (far below Fermi temperature TF) saturates to a value ε0 + εF. This extra εF=kTF is its Fermi energy.

The figure has been scaled in a way that the particle degeneracy factor, density, mass, etc. are all factored out and irrelevant.

This was generated using the same source code as File:Quantum ideal gas pressure 3d.svg.
Date
Source Own work
Author Nanite

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Category:CC-Zero#Quantum%20ideal%20gas%20chemical%20potential%203d.svgCategory:Self-published work
Category:Fermi-Dirac distribution Category:Bose-Einstein distribution Category:Bose-Einstein condensate Category:Classical ideal gas Category:Chemical potential
Category:Bose-Einstein condensate Category:Bose-Einstein distribution Category:CC-Zero Category:Chemical potential Category:Classical ideal gas Category:Fermi-Dirac distribution Category:Self-published work